摘要:
The crystallization process of some glasses in the ternary Na 2 O–SiO 2 –PbO system with good chemical stability that can be used for waste inertization was studied using X-ray diffraction (XRD), infrared spectroscopy (FT-IR), differential thermal analysis (DTA) and scanning electron microscopy. The parent glasses were characterized by XRD and FT-IR, and their vitreous state was determined. DTA measurements evidenced glass transition ( T g ) and crystallization temperatures ( T c ). The thermal treatments were conducted at vitreous transition temperature (400°C) and at highest effect of crystallization (650°C). XRD evidenced the lead and sodium silicate crystalline phases in samples treated at 650°C for 12h. Micrometer crystallites dispersed in the glass matrices have affected the transparence of glasses and made them opaque after treatment at 650°C. The influence of oxide quantities in compositions on the crystallization tendency was revealed. A PbO higher content than that of SiO 2 as well as lower Na 2 O content decreased the tendency of crystallization.
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