理解金纳米晶体的光热转换效率

        基于等离子体光热治疗是最有意义的应用对于贵金属纳米结构。表面等离子体波长、颗粒的大小、外壳涂层、以及自组装在金纳米晶体的光热转换效率上的影响是通过直接测量的温度，通过热电偶分析能量的平衡。当金纳米晶体的等离子体共振波长等于照射激光的波长时，金纳米晶体溶液的温度到达最大的75摄氏度。光热转换效率可以通过外壳涂层和自组装改变金纳米晶体等离子共振的能量。运用半导体材料的金纳米晶体涂层拥有的带宽能量小于照射光源的能量可以提高光热转换效率。

1、金纳米棒的生长用不同的纵向等离子体波长

在水溶液中用各向异性的氧化还原利用种子生长的方法生成金纳米棒用不同的纵向等离子体波长。波长在720、741、760、776、810、820、840、860、880、900、922以及957金纳米棒样品的获得是通过从纵向等离子体波长为957nm的纳米离子中还原出来的

For the growth of the Au NR sample with a longitudinal plasmon wavelength of 957nm, the seed solution was made by the addition of freshly prepared, ice-cold NaBH4 (0.6 mL,0.01 M) into a mixture composed of HAuCl4 (0.25 mL, 0.01 M) and cetyltrimethylammoniumbromide (CTAB, 9.75 mL, 0.1 M). The seed solution was kept at room temperature for 2 h before its use. The growth solution was prepared by the sequential addition of HAuCl4 (2 mL,0.01 M), AgNO3 (0.6 mL, 0.01 M), HCl (0.8 mL, 1.0 M),and ascorbic acid (0.32 mL, 0.1 M) into CTAB (40 mL, 0.1 M). After the resultant solution was mixed by swirling for 30 s, 0.3 mL of the seed solution was injected. The reaction solution was gently inversion-mixed for 2 min and then left undisturbed overnight.