<!DOCTYPE html>
<html>
<head>
<meta charset="UTF-8">
<title>select</title>
<style>
select{-webkit-border-radius:5px ; -moz-border-radius:5px;height:28px;
border-width:0px 21px 0px 5px;
-webkit-border-image:url("select-bg.jpg") 0 21 0 5;
-moz-border-image:url("select-bg.jpg") 0 21 0 5px;}
</style>
</head>
<body>
<select>
<option>北京</option>
<option>上海</option>
<option>广州</option>
</select>
</body>
<html>
<head>
<meta charset="UTF-8">
<title>select</title>
<style>
select{-webkit-border-radius:5px ; -moz-border-radius:5px;height:28px;
border-width:0px 21px 0px 5px;
-webkit-border-image:url("select-bg.jpg") 0 21 0 5;
-moz-border-image:url("select-bg.jpg") 0 21 0 5px;}
</style>
</head>
<body>
<select>
<option>北京</option>
<option>上海</option>
<option>广州</option>
</select>
</body>
</html>
demo图片: