For T.code ME21N there are below user exits select a user exit according to your requirement.
Exit Name Description
LMEDR001 - Enhancements to print program
LMELA002 - Adopt batch no. from shipping notification when posting a GR
LMELA010 - Inbound shipping notification: Transfer item data from IDOC
LMEQR001 - User exit for source determination
LMEXF001 - Conditions in Purchasing Documents Without Invoice Receipt
LWSUS001 - Customer-Specific Source Determination in Retail
M06B0001 - Role determination for purchase requisition release
M06B0002 - Changes to comm. structure for purchase requisition release
M06B0003 - Number range and document number
M06B0004 - Number range and document number
M06B0005 - Changes to comm. structure for overall release of requisn.
M06E0004 - Changes to communication structure for release purch. doc.
M06E0005 - Role determination for release of purchasing documents
ME590001 - Grouping of requsitions for PO split in ME59
MEETA001 - Define schedule line type (backlog, immed. req., preview)
MEFLD004 - Determine earliest delivery date f. check w. GR (only PO)
MELAB001 - Gen. forecast delivery schedules: Transfer schedule implem.
MEQUERY1 - Enhancement to Document Overview ME21N/ME51N
MEVME001 - WE default quantity calc. and over/ underdelivery tolerance
MM06E001 - User exits for EDI inbound and outbound purchasing documents
MM06E003 - Number range and document number
MM06E004 - Control import data screens in purchase order
MM06E005 - Customer fields in purchasing document
MM06E007 - Change document for requisitions upon conversion into PO
MM06E008 - Monitoring of contr. target value in case of release orders
MM06E009 - Relevant texts for "Texts exist" indicator
MM06E010 - Field selection for vendor address
MM06E011 - Activate PReq Block
MMAL0001 - ALE source list distribution: Outbound processing
MMAL0002 - ALE source list distribution: Inbound processing
MMAL0003 - ALE purcasing info record distribution: Outbound processing
MMAL0004 - ALE purchasing info record distribution: Inbound processing
MMDA0001 - Default delivery addresses
MMFAB001 - User exit for generation of release order
AMPL0001 - User subscreen for additional data on AMPL
MRFLB001 - Control Items for Contract Release Order