文章目录
Introduction and basic concepts
vocabulary
Phase
Definition
Classification
-
Fluid vs Solid Fluid vs Gas Proper volume/shape Free surface (surface tension) No freedom between molecules Occupies all the space available Does not flow. . . Compressibility/expandability Fluid = isotropic medium Density Compressibility Dynamic viscosity (variation with T for a liquid) System
Definition
Objective
Study the energy exchanges between the system and its surroundings through the boundary.
Composition of the system
Exchanges through the boundary
Some definitions
Physical parameters
State
Intensive & Extensive
Examples
| Separation |  |  |
|---|---|---|
| Mixture |  |  |
Specificities
Dependencies
State function
Definitnion:
- Total exact differential : $df = (\frac{∂f}{∂x})_y dx +(\frac{∂f}{∂y})_x dy $
- Independent of the path : ∆ f = f ( B ) − f ( A ) = ∫ A B d f ∆f = f(B) − f(A) = \int_{A}^{B}{}df ∆f=f(B)−f(A)=∫ABdf
- Equality of mixed partials : ∂ 2 f ∂ x ∂ y = ∂ 2 f ∂ y ∂ x \frac{∂^2f}{ ∂x∂y} = \frac{∂^2f}{ ∂y∂x} ∂x∂y∂2f=∂y∂x∂2f
Rule of phases
Fundamental quantities
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|---|---|
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Useful energies
Process
Definition
Some processes
| Basic process | Specific process |
|---|---|
 |  |
Reversibility
Definitinon
Reversible case & Irreversible case
| Reversible case | Irreversible case |
|---|---|
 |  |
comparison
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