3-热力学四定律-学习随笔(英文)

Laws of thermodynamics

“Zeroth” law

image-20200910055852165

image-20200910055925400


First law

The experiment

How

image-20200910055940443

Conclusion(s)

image-20200910055948951

c p c_p cpof water?

image-20200910055959024

Internal energy

Translation

image-20200910060009884

State function

image-20200910060025121

Internal energy

image-20200910060118789

Conclusion(s)

Conservative

image-20200910060125056

Mathematics

image-20200910060129431

Enthalpy

Isenthalpic process : Joule-Thomson process

image-20200910060139018

image-20200910060204317

Enthalpy

image-20200910060213170g)

Physically

image-20200910060220502

Exercise

image-20200910060238337

image-20200910060243536

Isochoric process

image-20200910060626565

Attention

image-20200910060711259

Isobaric process

image-20200910060819204

Attention

image-20200910060851101

Summary

image-20200910074539634


Second law

Direction of processes

image-20200910074656388

Variations

image-20200910074801215

Heat

image-20200910074916624

Entropy

image-20200910074953723

Created entropy

Case of cycles

image-20200910075231748

Created entropy

image-20200910075416925

2 cases

image-20200910075557726

Consequences

image-20200910075649468

Practical examples

image-20200910100906088

Adiabatic cooling of 2 solid bodies

image-20200910101129396

Application of second law

image-20200910101216441

Conclusion

image-20200910101306091

Irreversible expansion/compression of a gas

image-20200910101400503

image-20200910101431615

Hot water production

image-20200910101525491

image-20200910101543997

Evolution law

image-20200910101701187

Statements

Clausius’ statement

image-20200910101837608

Kelvin’s statement

image-20200910101905622

Classical statement

image-20200910101942956

Another form

image-20200910102027489

Third law

Nernst’s law

image-20200910102216656

Planck’s adjunction

image-20200910102240410


Summary

image-20200910102259697

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