3-热力学四定律-学习随笔(英文)

Laws of thermodynamics

“Zeroth” law

image-20200910055852165

image-20200910055925400


First law

The experiment

How

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Conclusion(s)

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c p c_p cpof water?

image-20200910055959024

Internal energy

Translation

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State function

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Internal energy

image-20200910060118789

Conclusion(s)

Conservative

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Mathematics

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Enthalpy

Isenthalpic process : Joule-Thomson process

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image-20200910060204317

Enthalpy

image-20200910060213170g)

Physically

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Exercise

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image-20200910060243536

Isochoric process

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Attention

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Isobaric process

image-20200910060819204

Attention

image-20200910060851101

Summary

image-20200910074539634


Second law

Direction of processes

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Variations

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Heat

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Entropy

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Created entropy

Case of cycles

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Created entropy

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2 cases

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Consequences

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Practical examples

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Adiabatic cooling of 2 solid bodies

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Application of second law

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Conclusion

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Irreversible expansion/compression of a gas

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image-20200910101431615

Hot water production

image-20200910101525491

image-20200910101543997

Evolution law

image-20200910101701187

Statements

Clausius’ statement

image-20200910101837608

Kelvin’s statement

image-20200910101905622

Classical statement

image-20200910101942956

Another form

image-20200910102027489

Third law

Nernst’s law

image-20200910102216656

Planck’s adjunction

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Summary

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