6-Real gases
文章目录
Exercise
Question
A quick calculation | Information |
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Ideal gas equation of state
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913230450.png)
WRONG!!!
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913230548.png)
What about heating?
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913230813.png)
Phase transiton
Phase transiton
Reminder about phases
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913231013.png)
First-order phase transition
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913231143.png)
Lots of modifications
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913231259.png)
The Clapeyron equation
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913232046.png)
Second-order phase transition
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913232231.png)
Consequences
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913232136.png)
Examples
![](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913232414.png)
Liquid - vapor | ![]() |
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Solid - liquid | ![]() |
Solid - vapor | ![]() |
A quick cycle
![image-20200913233437520](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913233437.png)
Comments
![image-20200913233513452](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913233513.png)
Drawbacks of ideal gases
![image-20200913233722875](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913233722.png)
Compressibility factor
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Case of CO2
![image-20200913233940830](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913233940.png)
Van der Waals
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Van der Waals isothermals in the (P, v) diagram
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![image-20200913234317964](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913234318.png)
Advantages/drawbacks
![image-20200913234349022](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913234349.png)
Let’s remove dimensions
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Theorem of corresponding states
![image-20200913234921153](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913234921.png)
Equation of state
Virial equation of state
![image-20200913235001335](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913235001.png)
Equations of state
![image-20200913235018035](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913235018.png)
Case of water - IAPWS 97
![image-20200913235035571](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913235035.png)
Computing
![image-20200913235052540](https://gitee.com/cao_jialing/Florine/raw/master/pic/20200913235052.png)