6-真实气体-学习随笔(英文)

6-Real gases

Exercise

Question

A quick calculationInformation

Ideal gas equation of state

WRONG!!!

What about heating?

Phase transiton

Phase transiton

Reminder about phases
First-order phase transition
Lots of modifications
The Clapeyron equation
Second-order phase transition
Consequences

Examples

Liquid - vapor
Solid - liquidimage-20200913233144611
Solid - vaporimage-20200913233217078
A quick cycle
image-20200913233437520
Comments
image-20200913233513452

Drawbacks of ideal gases

image-20200913233722875

Compressibility factor

image-20200913233759392image-20200913233814997

Case of CO2

image-20200913233940830

Van der Waals

image-20200913234012073image-20200913234024685

Van der Waals isothermals in the (P, v) diagram

image-20200913234106440
image-20200913234203683image-20200913234215877
image-20200913234245009image-20200913234258026
image-20200913234317964

Advantages/drawbacks

image-20200913234349022

Let’s remove dimensions

image-20200913234516996image-20200913234535038
image-20200913234834644image-20200913234843863

Theorem of corresponding states

image-20200913234921153

Equation of state

Virial equation of state

image-20200913235001335

Equations of state

image-20200913235018035

Case of water - IAPWS 97

image-20200913235035571

Computing

image-20200913235052540
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