StreamReader responseStream = File.OpenText(@"file.xml");
XPathNavigator resNav = (new XPathDocument(responseStream)).CreateNavigator();
// 解析带命名空间的节点
XmlNamespaceManager manager = new XmlNamespaceManager(resNav.NameTable);
manager.AddNamespace("ns", "http://www.wc3.com");
string value = resNav.SelectSingleNode("/ns:name", manager).Value;
大致的格式是“命名空间前缀:节点名称”