Install Software:
TortoiseGit:https://code.google.com/p/tortoisegit/
msysgit:http://msysgit.github.io/
Configure TFS account:
edit TFS User Profile > Credential, set Secondary Credential user name and password
Use
when Tortoise promote for user name, enter the secondary credential and password in above step
Reference:
http://kevintsengtw.blogspot.com/2013/07/team-foundation-service-git-tortoisegit.html#.UwM9s_mSxV0