MSTSC.exe is the executable of “Remote Desktop”. C:\windows\system32[lang]\ folder contains *.mui files, change the name from mstsc.exe.mui to mstsc.exe.old
It looks like there are a few system files that are having trouble. You are probably corrupting or missing one or both of these files (assuming Windows is installed on your C drive):
c:\windows\system32\en-us\mstsc.exe.mui
c:\windows\system32\en-us\mstscax.dll.mui
You could try to use SFC command to see if you have any corrupted system files:
Use the System File Checker tool to troubleshoot missing or corrupted system files on Windows Vista or on Windows 7
http://support.microsoft.com/kb/929833/en-us
Also you may run rsop.msc or gpresult /v to see if any policy is related to this.
mstsc 程序启动报错,系统找不到C:\windows\system32[lang]\ mstsc.exe.mui;
主要原因是系统文件出问题了。有可能丢失或者损坏如下2个系统文件。文件路径如下
c:\windows\system32\en-us\mstsc.exe.mui
c:\windows\system32\en-us\mstscax.dll.mui;
利用工具检查或者修复这2个文件即可。