web.config作为一个xml文档
可以用XmlDocument对它修改
XmlDocument xDoc = new XmlDocument();
xDoc.Load(Server.MapPath("Web.config"));
XmlNode app=xDoc.SelectSingleNode("/configuration/appSettings/add[@key='abc']");
app.Attributes["value"].Value="haha";
xDoc.Save(Server.MapPath("Web.config"));
转载于:https://www.cnblogs.com/ycmoon/archive/2010/03/05/1678889.html