python数据拟合方法_使用python进行非线性回归-有什么简单的方法可以更好地拟合此数据？...

I have some data that I want to fit so I can make some estimations for the value of a physical parameter given a certain temperature.

I used numpy.polyfit for a quadratic model, but the fit isn't quite as nice as I'd like it to be and I don't have much experience with regression.

The x axis is temperature (in C) and the y axis is the parameter, which we'll call S. This is experimental data, but in theory S should tends towards 0 as temperature increases and reach 1 as temperature decreases.

My question is: How can I fit this data better? What libraries should I use, what kind of function might approximate this data better than a polynomial, etc?

I can provide code, coefficients of the polynomial, etc, if it's helpful.

Here is a Dropbox link to my data. (Somewhat important note to avoid confusion, although it won't change the actual regression, the temperature column in this data set is Tc - T, where Tc is the transition temperature (40C). I converted this using pandas into T by calculating 40 - x).

解决方案

This example code uses an equation that has two shape parameters, a and b, and an offset term (that does not affect curvature). The equation is "y = 1.0 / (1.0 + exp(-a(x-b))) + Offset" with parameter values a = 2.1540318329369712E-01, b = -6.6744890642157646E+00, and Offset = -3.5241299859669645E-01 which gives an R-squared of 0.988 and an RMSE of 0.0085.

The example contains your posted data with Python code for fitting and graphing, with automatic initial parameter estimation using the scipy.optimize.differential_evolution genetic algorithm. The scipy implementation of Differential Evolution uses the Latin Hypercube algorithm to ensure a thorough search of parameter space, and this requires bounds within which to search - in this example code, these bounds are based on the maximum and minimum data values.

import numpy, scipy, matplotlib

import matplotlib.pyplot as plt

from scipy.optimize import curve_fit

from scipy.optimize import differential_evolution

import warnings

xData = numpy.array([19.1647, 18.0189, 16.9550, 15.7683, 14.7044, 13.6269, 12.6040, 11.4309, 10.2987, 9.23465, 8.18440, 7.89789, 7.62498, 7.36571, 7.01106, 6.71094, 6.46548, 6.27436, 6.16543, 6.05569, 5.91904, 5.78247, 5.53661, 4.85425, 4.29468, 3.74888, 3.16206, 2.58882, 1.93371, 1.52426, 1.14211, 0.719035, 0.377708, 0.0226971, -0.223181, -0.537231, -0.878491, -1.27484, -1.45266, -1.57583, -1.61717])

yData = numpy.array([0.644557, 0.641059, 0.637555, 0.634059, 0.634135, 0.631825, 0.631899, 0.627209, 0.622516, 0.617818, 0.616103, 0.613736, 0.610175, 0.606613, 0.605445, 0.603676, 0.604887, 0.600127, 0.604909, 0.588207, 0.581056, 0.576292, 0.566761, 0.555472, 0.545367, 0.538842, 0.529336, 0.518635, 0.506747, 0.499018, 0.491885, 0.484754, 0.475230, 0.464514, 0.454387, 0.444861, 0.437128, 0.415076, 0.401363, 0.390034, 0.378698])

def func(x, a, b, Offset): # Sigmoid A With Offset from zunzun.com

return 1.0 / (1.0 + numpy.exp(-a * (x-b))) + Offset

# function for genetic algorithm to minimize (sum of squared error)

def sumOfSquaredError(parameterTuple):

warnings.filterwarnings("ignore") # do not print warnings by genetic algorithm

val = func(xData, *parameterTuple)

return numpy.sum((yData - val) ** 2.0)

def generate_Initial_Parameters():

# min and max used for bounds

maxX = max(xData)

minX = min(xData)

maxY = max(yData)

minY = min(yData)

parameterBounds = []

parameterBounds.append([minX, maxX]) # search bounds for a

parameterBounds.append([minX, maxX]) # search bounds for b

parameterBounds.append([0.0, maxY]) # search bounds for Offset

# "seed" the numpy random number generator for repeatable results

result = differential_evolution(sumOfSquaredError, parameterBounds, seed=3)

return result.x

# generate initial parameter values

geneticParameters = generate_Initial_Parameters()

# curve fit the test data

fittedParameters, pcov = curve_fit(func, xData, yData, geneticParameters)

print('Parameters', fittedParameters)

modelPredictions = func(xData, *fittedParameters)

absError = modelPredictions - yData

SE = numpy.square(absError) # squared errors

MSE = numpy.mean(SE) # mean squared errors

RMSE = numpy.sqrt(MSE) # Root Mean Squared Error, RMSE

Rsquared = 1.0 - (numpy.var(absError) / numpy.var(yData))

print('RMSE:', RMSE)

print('R-squared:', Rsquared)

##########################################################

# graphics output section

def ModelAndScatterPlot(graphWidth, graphHeight):

f = plt.figure(figsize=(graphWidth/100.0, graphHeight/100.0), dpi=100)

axes = f.add_subplot(111)

# first the raw data as a scatter plot

axes.plot(xData, yData, 'D')

# create data for the fitted equation plot

xModel = numpy.linspace(min(xData), max(xData))

yModel = func(xModel, *fittedParameters)

# now the model as a line plot

axes.plot(xModel, yModel)

axes.set_xlabel('X Data') # X axis data label

axes.set_ylabel('Y Data') # Y axis data label

plt.show()

plt.close('all') # clean up after using pyplot

graphWidth = 800

graphHeight = 600

ModelAndScatterPlot(graphWidth, graphHeight)