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Sample Al2O3 SiO2 Fe2O3 TiO2 CaO Al/Si
HAFA 49.88 38.72 2.02 1.38 2.76 1.29

PHAFA 74.06 20.98 0.19 1.06 0.13 3.53

Table 2. Mineralogical composition of HAFA and PHAFA (wt%) .
Sample Mullite Corundum Amorphous silica
HAFA 50.80 14.87 34.33

PHAFA 76.57 22.41 1.02

Sample Al2O3 SiO2 Na2O Al/Si
140 °C 83.01 4.56 353.64 2.06 
160 °C 90.33 2.02 344.32 1.95
180 °C 96.15 1.47 340.70 1.82
200 °C 132.47 1.23 339.58 1.07

220 °C 134.17 1.12 338.28 0.95

Sample Al2O3 SiO2 Na2O Al/Si
15 min 105.35 1.77 343.52 1.64
30 min 119.79 1.68 341.28 1.38
60 min 128.43 1.54 340.61 1.12
90 min 132.47 1.23 339.78 1.07

120 min 133.09 1.16 339.04 1.02

Composition Al2O3 SiO2 Fe2O3 TiO2 CaO Na2O Al/Si

Content (wt%) 29.85 31.42 0.38 2.61 0.31 20.72 0.95

T/°C Fitting coefficient R2
External
diffusion control Product layer
diffusion control Chemical
reaction control
120 0.9284 0.9502 0.9969
140 0.9163 0.9618 0.9971
160 0.9429 0.9405 0.9925
180 0.9310 0.9546 0.9897
Table 7. Fitting coefficients R2 of dissolution data of corundum at 190–220 °C.


T/°C Fitting coefficient R2
External
diffusion control Product layer
diffusion control Chemical
reaction control
190 0.9540 0.9490 0.9919
200 0.9489 0.9573 0.9927
210 0.9223 0.9612 0.9973
220 0.9352 0.9378 0.9901