python装库时出现错误error: could not install packages due to an oserror:

error: could not install packages due to an oserror: Could not find a suitable TLS CA certificate bundle, invalid path: 

原因是：postgresql 安装以某种方式更新了系统环境变量。

解决办法：

1、更新系统环境CURL_CA_BUNDLE变量 cacert.pem，

找到证书束的有效路径，修改系统环境变量

import certifi
print(certifi.where())

2、重启计算机

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python - Could not install packages due to an EnvironmentError: Could not find a suitable TLS CA certificate bundle, invalid path - Stack Overflow