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传质过程【Mass Transfer】
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Chem-To-Math
Chem is not try. Chem should be math.
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菲克扩散(第一)定律【Fick's (First) Law of Binary Diffussion】
菲克扩散(第一)定律Fick’s (First) Law of Binary Diffussion物质扩散通量Diffusion flux表达通式 jjA=−ρDAB∇wAjjA=−ρDAB∇wA\pmb j_A=-\rho \mathscr{D} _{AB} {\nabla } w_A 在单位时间内物质 A 通过垂直于扩散方向的单位截面积的扩散物质流量,kg⋅m−2⋅s−1kg⋅m...原创 2018-06-23 11:28:31 · 9854 阅读 · 0 评论 -
傅里叶热传导定律【Fourier's Law of Heat Conduction】
傅里叶热传导定律Fourier’s Law of Heat Conduction热通量Heat Flux 表达式 qq=−k∇Tqq=−k∇T\pmb q=-k{\nabla }T其中qqqq \pmb q 是单位面积上的热通量, W⋅m−2W·m−2W·m^{−2}, kkk 是材料的热传导系数, W⋅m−1⋅K−1W·m−1·K−1W·m^{−1}·K^{−1}, ...原创 2018-06-23 10:50:30 · 34183 阅读 · 0 评论 -
流体传质方程【Mass Transfer Equation】
流体传质方程Equation of Continuity for Species αα \alpha in terms of jjαjjα \pmb j_\alpha控制方程表达通式: ρDwαDt=−∇⋅jjα+rαρDwαDt=−∇⋅jjα+rα\rho \dfrac {D w_\alpha}{Dt}=-\nabla \cdot \pmb j_\alpha + r_\alpha...原创 2018-06-24 03:45:49 · 1377 阅读 · 0 评论 -
传质方程
传质方程Equation of Continuity for Species A with Constant ρDABρDAB\rho \mathscr{D}_{AB} in terms of wAwAw_A控制方程表达通式: ρDwADt=ρDAB∇2wA+rAρDwADt=ρDAB∇2wA+rA\rho \dfrac {Dw_A}{Dt}=\rho \mathscr{D}_{AB}\...原创 2018-06-24 03:58:09 · 1961 阅读 · 1 评论 -
恒电势电流曲线和浓度分布(i-t curve)
Test condition: 1. No stirring; 2. The concentration of reactant at the electrode surface is always 0. Half reaction: O+ne→R(a)(a)O+ne→RO+ne\rightarrow R \tag{a} The equation of the limiting cur...原创 2018-07-18 03:18:59 · 3365 阅读 · 0 评论 -
Half-wave potential(半波电位)推导之一
Test conditionNo stirring;Fast kineticsStep to an arbitrary potential suddenlyCottrell-like experimentHalf reaction:(1)O+ne⇌RO+ne{\rightleftharpoons} R \tag{1}O+ne⇌R(1)In the case of Nerstian...原创 2018-10-29 19:05:42 · 3760 阅读 · 0 评论