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工程数学
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Chem-To-Math
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泊松-玻尔兹曼方程的提出
泊松-玻尔兹曼Poisson–Boltzmann方程的提出1.简要历史回顾1.1 基本原理1.2 方程推导1.简要历史回顾泊松-玻尔兹曼方程是用来计算电解质溶液中离子浓度和电荷密度分布的一个微分方程,其基本形式为∇2ϕ(r)=−4πϵ∑ici0ziqe−βziqϕ(r)(1)\nabla^2\phi(\textbf r)=-\frac{4\pi}{\epsilon}\sum_{i} c_i^0z_iqe^{-\beta z_iq\phi(\textbf r)} \tag{1}∇2ϕ(r)=−ϵ4πi原创 2021-10-07 23:07:17 · 4092 阅读 · 1 评论 -
Fourier transform 复数形式
Fourier transform 复数形式Z(ω)=∫−∞∞f(t)e−jωtdt Z(\omega)=\int ^{\infty}_{-\infty}f(t)e^{-j\omega t}dtZ(ω)=∫−∞∞f(t)e−jωtdtwheree−jωt=cos(ωt)−jsin(ωt)e^{-j\omega t}=cos(\omega t)-j sin(\omega t)e−jωt=cos(ωt)−jsin(ωt)ThenZ(ω)=∫−∞∞f(t)[cos(ωt)−jsin(ωt)]dt Z原创 2021-09-21 20:56:32 · 282 阅读 · 0 评论 -
Convolution Property of the Fourier Transform
Two functions of f(t)f(t)f(t) and g(t)g(t)g(t)The Fourier transform of f(t)f(t)f(t) isF(f(t))=F(ω)=∫−∞∞f(t)exp(−jωt)dt\mathcal{F}(f(t))=F(\omega)=\int ^{\infty} _{-\infty}f(t)exp(-j\omega t)dtF(f(t))=F(ω)=∫−∞∞f(t)exp(−jωt)dtThe Fourier transform of g(t原创 2021-09-19 21:23:05 · 164 阅读 · 0 评论 -
Derivative property of the Fourier transform
f(t)f(t)f(t) has the property:The domain is (∞,−∞)(\infty, -\infty)(∞,−∞)The integral of f(t)f(t)f(t) is limited∫−∞∞f(t)dt=A\int ^{\infty} _{-\infty}f(t)dt= A∫−∞∞f(t)dt=Aandlimt→∞f(t)=0{ \lim_{t \to \infty} f(t)=0}t→∞limf(t)=0The Fourier transfor原创 2021-09-19 20:51:18 · 149 阅读 · 0 评论 -
Inverse Fourier transform
DefinitionF(ω)=∫−∞∞f(t)exp(−jωt)dtF(\omega)=\int ^{\infty} _{-\infty}f(t)exp(-j\omega t)dtF(ω)=∫−∞∞f(t)exp(−jωt)dtInverse Fourier transformf(t)=F−1(F(ω))=12π∫−∞∞f(ω)exp(jωt)dωf(t)=\mathcal F ^{-1}( F(\omega))=\frac {1}{2\pi}\int ^{\infty} _{-\infty}f(\原创 2021-09-18 17:52:33 · 343 阅读 · 0 评论 -
恒电势电流曲线和浓度分布(i-t curve)
Test condition: 1. No stirring; 2. The concentration of reactant at the electrode surface is always 0. Half reaction: O+ne→R(a)(a)O+ne→RO+ne\rightarrow R \tag{a} The equation of the limiting cur...原创 2018-07-18 03:18:59 · 3365 阅读 · 0 评论 -
复杂的拉普拉斯逆变换
Laplace Inverse Transformation (LIT)L(1πte−a2/4t)=e−ass, a>0\mathcal{L}(\frac{1}{\sqrt{\pi t}}\text{e}^{-a^2/4t})=\frac{\text{e}^{-a\sqrt{s}}}{\sqrt{s}},~~ a>0L(πt1e−a2/4t)...原创 2019-01-26 18:16:53 · 5527 阅读 · 0 评论