Amino acids
Amino acids
general structure of α − \alpha - α−Amino Acids
classification of common α − \alpha - α−Amino Acids
-
nonpolar,aliphatic
name three-letters abbreviation one-letter abbreviation Glycine甘氨酸 Gly G Alanine丙氨酸 Ala A Proline脯氨酸 Pro P Valine缬氨酸 Val V Leucin亮氨酸 Leu L Isoleucine异亮氨酸 Ile I Methionine甲硫氨酸 Met M 
-
aromatic
name three-letters abbreviation one-letter abbreviation Phenylalanine苯丙氨酸 Phe F Tyrosine酪氨酸 Tyr Y Tryptophan色氨酸 Trp W can be studied via ultraviolet light
-
polar,uncharged
name three-letters abbreviation one-letter abbreviation Serine丝氨酸 Ser S Thtronine苏氨酸 Thr T Cysteine巯基丙氨酸 Cys C Asparagine天冬氨酸 Asn N Glutamine谷氨酰胺 Gln Q 
-
positively charged(basic)
name three-letters abbreviation one-letter abbreviation Lysine赖氨酸 Lys K Arginine精氨酸 Arg R Histidine组氨酸 His H 
-
negatively charged(acidic)
name three-letters abbreviation one-letter abbreviation Aspartate天冬氨酸 Asp D Glutamate谷氨酸 Glu E 
-
classification of Amino Acids by polarity
-
average molecular weight:110
stereochemistry of Amino Acids
L-D
-
− N + H 3 -\mathop{N}\limits^{+}H_3 −N+H3 isomer right D left L
R-S
-
1 → 2 → 3 → 4 1\rightarrow 2\rightarrow 3\rightarrow 4 1→2→3→4 − S H , − O C O R , − O R , − O H , − N H R , − N H 2 , − C O O R , − C O O H , − C O N H 2 , − C H O , − C H R O H , − C H 2 O H , − C 6 H 5 , − C H 3 , − T , − D , − H -SH, -OCOR, -OR, -OH, -NHR, -NH_2, -COOR, -COOH, -CONH_2, -CHO, -CHROH, -CH_2OH, -C_6H_5, -CH_3, -T, -D, -H −SH,−OCOR,−OR,−OH,−NHR,−NH2,−COOR,−COOH,−CONH2,−CHO,−CHROH,−CH2OH,−C6H5,−CH3,−T,−D,−H - Amino Acids with two chiral centers
R,S-nomenclature of Ile and Thr:
Reactions of Amino Acids
α − \alpha - α−Carboxyl group reactions
- Amino Acids + N H 3 → NH_3\rightarrow NH3→ Amide
- Amino Acids + R ′ − N H 2 → R^{'}-NH_2\rightarrow R′−NH2→ Substituted amide
- Amino Acids + R ′ − O H → R^{'}-OH\rightarrow R′−OH→ Ester
α − \alpha - α−Amino group reactions
- the Ninhydrin reaction
-
-
oxidative deamination of the α − \alpha - α−amino group :
-
side chains reactions
-
-
保护巯基:
407
被折叠的 条评论
为什么被折叠?
到【灌水乐园】发言
