At Central Administration site, you can add the user that belongs to the domain server.
etc. Domain/UserA
Domain/UserB
Domain/UserC
At site you must add the user that you want the user to get access.
etc. If you want A then Add Domain/UserA
if you want D then Add Domain/UserD note UserD isn't added into Central Administration site.
if you don't add userB, B can not access it.