btArray[i] = Convert.ToByte(strArray[i],16);

namespace ConsoleApplication7
{
    class Program
    {
        static void Main(string[] args)
        {
            String str = "61 41";
            String[] strArray = str.Split(' ');
            byte[] btArray = new byte[strArray.Length];
            for (int i = 0; i < strArray.Length;i++ )
            {
                btArray[i] = Convert.ToByte(strArray[i],16);
                //Console.WriteLine(bt);
            }

        }
    }
}