好的，以下是使用MATLAB语言定义将RGB转换为HSI颜色空间的函数rgb2hsi：
```matlab
function [h,s,i] = rgb2hsi(r,g,b)
%RGB2HSI Convert red-green-blue colors to hue-saturation-intensity.
% HSI = RGB2HSI(RGB) converts the RGB image RGB (which is m-by-n-by-3)
% to the HSI (hue-saturation-intensity) color space. RGB values are
% assumed to be in the range of 0 to 1.
%
% The HSI color space, also known as HSL (hue-saturation-lightness),
% separates color information (hue) from intensity information (saturation
% and intensity). Hue is defined as the angle of the color on a color wheel,
% saturation is the amount of color present, and intensity is the brightness
% of the color.
%
% Class Support
% -------------
% Input RGB can be of class uint8, uint16, single, or double. Output HSI
% is double.
%
% Example
% -------
% % Convert an RGB image to HSI color space
% RGB = imread('peppers.png');
% HSI = rgb2hsi(RGB);
%
% See also HSI2RGB, RGB2LAB, RGB2NTSC, RGB2XYZ, RGB2YCBCR, RGB2GRAY.
% Validate inputs
validateattributes(r, {'uint8', 'uint16', 'double', 'single'}, {'real', 'nonsparse', 'nonempty', '>=', 0, '<=', 1}, mfilename, 'R', 1);
validateattributes(g, {'uint8', 'uint16', 'double', 'single'}, {'real', 'nonsparse', 'nonempty', '>=', 0, '<=', 1}, mfilename, 'G', 2);
validateattributes(b, {'uint8', 'uint16', 'double', 'single'}, {'real', 'nonsparse', 'nonempty', '>=', 0, '<=', 1}, mfilename, 'B', 3);
% Initialize output variables
h = zeros(size(r));
s = zeros(size(r));
i = zeros(size(r));
% Calculate hue
theta = acos((2*r-g-b)./(2*sqrt((r-g).^2 + (r-b).*(g-b))));
h(b > g) = 2*pi - theta(b > g);
h = h/(2*pi);
% Calculate saturation
minRGB = min(min(r,g),b);
s(minRGB > 0) = 1 - minRGB(minRGB > 0)./i(minRGB > 0);
% Calculate intensity
i = (r + g + b)/3;
end
```
在这个函数中，我们首先验证输入的RGB值是否符合要求，然后初始化输出变量，并计算HSI颜色空间的三个分量：色调（hue）、饱和度（saturation）和亮度（intensity）。
注意，这个函数中的算法是从RGB转换到HSI的标准算法，但在某些情况下可能会产生不正确的结果。如果需要更准确的RGB到HSI转换算法，请参考相关文献。
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