计算机文献汇报ppt,文献汇报PPT.ppt

文献汇报PPT

* 4. conclusions Nano-structured calcium tungstate was synthesized by the co-precipitation . The application of CaWO4 as a catalyst support for Pt. Pt/CaWO4-graphite catalyst exhibited better electrochemical activity for oxygen reduction reaction in H2SO4 solutio compared to Pt/graphite. * Thank you for your attention! * * Paper Review 李俊乾 化学工程(专) Synthesis, characterization and electrochemical studies of nano-structured CaWO4 as platinum support for oxygen reduction reaction (纳米钨酸钙的合成、表征和其负载铂对氧还原反应的电催化) * Literature source * Contents Introduction 1 2 Experimental section 1 Conclusions 2 3 4 Results and discussion * 1. Introduction In recent years, proton exchange membrane fuel cells(PEMFCs) have been recognized as promising devices for portable and transport applications due to their good energy conversion efficiency, high power density, low operating temperature, and easy transport. PEMFC’S working principle: * 1. Introduction The cathodic reaction of oxygen reduction reaction (ORR) The anodic reaction of hydrogen oxidation reaction for H2+2M→2MH 2MH→2M+2H++2e- O2+H++M+e-→MHO2 MHO2+H++e-→MO+H2O MO+H++e-→MOH MOH+H++e-→M+H2O Electrocatalytic reaction mechanism: * In the fuel cell in the work process, the platinum catalyst active surface area will be gradually reduced, resulting in the attenuation of fuel cell performance. the properties of Pt/PtM alloy recession schematic diagram * Experimental section 2 * 2. Experimental section Synthesis of nanostructured CaWO4: 80°C pH=7 white precipitates were collected by centrifuga