m_ConfigFullPath XPathNavigator.SelectSingleNode.Value;

(string configfile ="Config.xml")
        {
            m_ConfigfileName = configfile;
            StringBuilder FileFullPath = new StringBuilder(Application.StartupPath);
            FileFullPath.Append(@"\").Append(m_ConfigfileName);
            m_ConfigFullPath = FileFullPath.ToString();
        }

XPathDocument   m_ConfigDoc = new XPathDocument(m_ConfigFullPath);
 XPathNavigator   m_ConfigNavigator = m_ConfigDoc.CreateNavigator();

configNode = System.Xml.XPath.XPathNavigator.SelectSingleNode

 XPathNavigator node = ConfigNavigator.SelectSingleNode("/Config/Configure/@value");
string m_SecondCheck = node.Value;