pde与波长 sipm 关系_基于SiPM和TCMPC的时间分辨拉曼散射测量技术研究

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苗泉龙, 代雷, 李佰成, 赵天琦, 梁琨, 杨茹, 韩德俊. 基于SiPM和TCMPC的时间分辨拉曼散射测量技术研究[J]. 光谱学与光谱分析, 2018,38(5): 1444-1450.

MIAO Quan-long, DAI Lei, LI Bai-cheng, ZHAO Tian-qi, LIANG Kun, YANG Ru, HAN De-jun. Time-Resolved Raman Scattering Measurement Based on SiPM and TCMPC Method[J]. Spectroscopy and Spectral Analysis, 2018,38(5): 1444-1450.

Doi:10.3964/j.issn.1000-0593(2018)05-1444-07

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基于SiPM和TCMPC的时间分辨拉曼散射测量技术研究

苗泉龙1, 代雷1, 李佰成1, 赵天琦1, 梁琨1,2, 杨茹1,2, 韩德俊1,2,*

1. 北京师范大学核科学与技术学院, 北京 100875

2. 北京市辐射中心, 北京 100875

*通讯联系人 e-mail: djhan@bnu.edu.cn

作者简介: 苗泉龙, 1991年生, 北京师范大学核科学与技术学院硕士研究生 e-mail: 314647104@qq.com

收稿日期: 2017-06-08

基金: 国家自然科学基金项目(11275026)和北京市科技委项目(Z141100003414007)资助

摘要

报道了一种基于硅光电信增管(SiPM)的时间相关多光子计数(TCMPC)技术并将其应用于时间分辨拉曼散射测量。 相比于常规基于光电倍增管(PMT)或单光子雪崩二极管(SPAD)的时间相关单光子(TCSPC)技术, 由于SiPM可以分辨信号脉冲的具体光子数, 基于SiPM的TCMPC技术消除了信号脉冲包含的光子数必须小于等于1的限制, 光子计数效率提高了10倍以上, 大大节省了测量时间。 此外, 多光子测量比单光子测量能够得到更好的时间分辨率, 时间分辨拉曼散射系统的仪器响应函数(IRF)从单光子81.4 ps缩短至双光子59.7 ps, 因而可以用更窄的时间门限抑制荧光本底等噪声对拉曼散射测量的影响。 使用TCMPC技术测量CCl4在0.5和1.5 p.e.两个不同光子数阈值的拉曼峰的峰本比, 后者较高的光子数阈值能进一步降低SiPM暗计数噪声的影响, 增加了拉曼信号测量的信噪比, 测量得到的CCl4 459 cm-1拉曼峰的峰本比是前者的6.4倍。 将所述新的拉曼散射测量技术与基于PMT和锁相放大器(LIA)的传统拉曼散射测量技术进行了比较研究, 前者由于可以使用仅有数十皮秒的测量门限, 可以有效抑制荧光、 环境杂散光和SiPM暗计数等噪声的影响, 所得光谱具有更好的峰本比, 测得CCl4的459 cm-1拉曼峰和Si的一阶拉曼峰的峰本比分别是后者的3.9倍和5.5倍。

关键词:

硅光电信增管; 时间相关单位光子; 时间相关多光子计数; 时间分辨; 拉曼散射; 仪器响应函数; 峰本比

中图分类号:O433.1

文献标志码:A

Time-Resolved Raman Scattering Measurement Based on SiPM and TCMPC Method

MIAO Quan-long1, DAI Lei1, LI Bai-cheng1, ZHAO Tian-qi1, LIANG Kun1,2, YANG Ru1,2, HAN De-jun1,2,*

1. College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875, China

2. Beijing Radiation Center, Beijing 100875, China

Abstract

This paper reports a time-correlated multi-photon counting (TCMPC) technique based on SiPM and its application to time-resolved Raman scattering measurements. Compared with conventional time-correlated single photon counting (TCSPC) technique by using photomultiplier (PMT) or single photon avalanche diode (SPAD) as photon detector, SiPM can distinguish the specific photon-number of the signal pulse, the TCMPC technique based on SiPM eliminates the limitation of the number of photons contained in signal pulse, which must be less than or equal to 1, leading to an increment of the photon counting efficiency by more than 10 times, and greatly reduces the measurement time. In addition, the instrument response function (IRF) of the time-resolved Raman scattering system is enhanced from 81.4 ps for single-photon to 59.7 ps for two-photon detection due to higher time resolution for multi-photon counting than single-photon counting measurement. As a result, it is possible to use a narrower measuring time span to suppress the fluorescence background, a kind of noise that usually occurs in conventional Raman spectroscopy. The TCMPC technique is used to measure the peak-to-background ratio of Raman spectroscopy of CCl4 with different photon numbers of 0.5 p.e. and 1.5 p.e., because the later has a higher photo-electron threshold number that can further reduce the effect of SiPM dark