NOAA实验室空气样本分析:探寻北极永久冻土融化潜在威胁

CARVE: L2 Atmospheric Gas Concentrations, Airborne Flasks, Alaska, 2012-2015

简介

本数据集提供了北极碳储层脆弱性实验 (CARVE) 在阿拉斯加和加拿大北极地区进行的空中飞行活动所提供的大气二氧化碳 (CO2)、甲烷 (CH4)、一氧化碳 (CO)、氢分子 (H2)、氧化亚氮 (N2O)、六氟化硫 (SF6) 和其他微量气体的摩尔分数(即“浓度”)。CARVE 飞行活动于 2012 年至 2015 年 3 月至 11 月期间进行,旨在研究大气气体丰度的季节性和年际变化。数据来源于 CARVE 飞机上可编程烧瓶包 (PFP​​) 采集的空气样本的实验室测量结果。空气样本的采集间隔为战略性间隔,以配合感兴趣的地面站点上空飞行,或遇到有趣的地球物理条件时进行。虽然大多数样本是在行星边界层 (PBL) 地表附近采集的,但几乎每次飞行也会在自由对流层采集样本。每次飞行至少采集 12 个瓶装样本。在北极永久冻土带(PFP)采集的空气样本全部由位于科罗拉多州博尔德的美国国家海洋和大气管理局(NOAA)地球系统研究实验室(ESRL)全球监测部门的自动化系统进行分析,该部门还负责分析来自 NOAA/ESRL 全球温室气体参考网络的样本。该数据集中包含的测量数据对于理解北极碳循环的变化以及北极永久冻土融化带来的潜在威胁至关重要。

摘要

Table 1: CARVE file naming convention. Example file name: carve_Flask_L2_b23_20121001_20160807204049.nc

Name element

Example value

Units

Project name

carve

Instrument

Flask

Processing level

L2

Build ID

b23

Flight date start

20121001

yyyymmdd

Processing date and time

20160807204049

yyyymmddhhmmss

Data variables

Each file contains 14 geolocation and ancillary variables and 69 science measurement variables described in Table 2.

Table 2. Data variables in each netCDF file. Fill value or missing data were set to -999.9 for all variables.

Variable name

Description

Units

Geolocation and ancillary measurements

center_lat

latitude

decimal degrees North

center_lat_standard_error

latitude standard error

decimal degrees North

center_lon

longitude

decimal degrees East

center_lon_standard_error

longitude standard error

decimal degrees East

height

height of aircraft above ground

meters

height_standard_error

height standard error

meters

geolocation_qc

geolocation status flag

0 = Success, 1 = Error

time

time of sample collection

seconds since 1980-1-6 0:0:0

elevation

surface elevation

meters

event_number

NOAA database event number

intake_height

sample intake height

meters

flask_id

sample container ID

sample_method

sample collection method

site_code

sample site code

Science measurements

benz

benzene (C6H6)

parts per trillion (ppt) *

brfm

bromoform (CHBr3)

ppt

c2f6

hexafluoroethane (CF3CF3)

ppt

c2h2

ethyne (acetylene; C2H2)

ppt

c2h4

ethene (ethylene; C2H4)

ppt

c2h6

ethane (C2H6)

ppt

c3h6

propene (propylene; C3H6)

ppt

c3h8

propane (C3H8)

ppt

ccl4

carbon tetrachloride (tetrachloromethane; CCl4)

ppt

cf4

carbon tetraflouride (tetrafluoromethane; CF4)

ppt

ch2brcl

bromochloromethane (CH2BrCl)

ppt

ch3i

methyl iodide (CH3I)

ppt

ch4

methane (CH4)

parts per billion (ppb) *

chlf

chloroform (CHCl3)

ppt

co

carbon monoxide (CO)

ppb

co2

carbon dioxide (CO2)

parts per million (ppm) *

co2c13

d13C  of CO2

ppm

co2c14

d14C of CO2

ppm

co2o18

d18O of CO2

ppm

cs2

carbon disulfide (CS2)

ppt

dibr

dibromomethane (CH2Br2)

ppt

dicl

dichloromethane (CH2Cl2)

ppt

f112

CFC-112 (CCl3CClF2)

ppt

f113

CFC-113 (CCl2FCClF2)

ppt

f114

CFC-114 and CFC-114a (ClF2CCF2Cl)

ppt

f115

CFC-115 (CClF2CF3)

ppt

f11a

CFC-11 (ion 101; CCl3F)

ppt

f11b

CFC-11 (ion 103; CCl3F)

ppt

f124

HCFC-124 (CHClFCF3)

ppt

f125

HFC-125 (CHF2CF3)

ppt

f13

CFC-13 (CClF3)

ppt

f134

HFC-134 (CHF2CHF2)

ppt

f134a

HFC-134a (CH2FCF3)

ppt

f141b

HCFC-141b (CH3CCl2F)

ppt

f142b

HCFC-142b (CH3CF2Cl)

ppt

f143a

HFC-143a (CH3CF3)

ppt

f152a

HFC-152a (CH3CHF2)

ppt

f160

chloroethane (CH3CH2Cl)

ppt

f227e

HFC-227ea (CF3CHFCF3)

ppt

f23

HFC-23 (CHF3)

ppt

f236fa

HFC-236fa (CF3CH2CF3)

ppt

f32

HFC-32 (CH2F2)

ppt

f365m

HFC-365mfc (CH3CF2CH2CF3)

ppt

fc12

CFC-12 (CCl2F2)

ppt

h1211

bromochlorodifluoromethane (halon 1211; CBrClF2)

ppt

h1301

bromotrifluoromethane (halon 1301; CF3Br)

ppt

h2

hydrogen (H2)

ppb

h2402

dibromotetrafluoroethane (halon 2402; CBrF2CBrF2)

ppt

hf133a

HCFC-133a (CH2ClCF3)

ppt

hf21

HCFC-21 (CHCl2F)

ppt

hf22

HCFC-22 (CHF2Cl)

ppt

ic4h10

i-butane (i-C4H10)

ppt

ic5h12

i-pentane (i-C5H12)

ppt

mcfa

methyl chloroform (ion 97; CH3CCl3)

ppt

mebr

methyl bromide (CH3Br)

ppt

mecl

methyl chloride (CH3Cl)

ppt

n2o

nitrous oxide (N2O)

ppb

nc4h10

n-butane (n-C4H10)

ppt

nc5h12

n-pentane (n-C5H12)

ppt

nc6h14

n-hexane (n-C6H14)

ppt

nf3

nitrogen trifluoride (NF3)

ppt

ocs

carbonyl sulfide (COS)

ppt

p218

perfluoropropane (C3F8)

ppt

pce

tetrachloroethylene (C2Cl4)

ppt

sf6_ccgg

sulfur hexafluoride (SF6)

ppt

sf6_hats

sulfur hexafluoride (SF6)

ppt

so2f2

sulfuryl fluoride (SO2F2)

ppt

tce

trichloroethylene (C2HCl3)

ppt

tol

toluene (C7H8)

ppt

*   parts per million – ppm – micromol of gas per mol of dry air – 10-6

     parts per billion – ppb – nanomol of gas per mol of dry air – 10-9

     parts per trillion – ppt – picmol of gas per mol of dry air – 10-12

The netcdf files also include a QC flag for each analyte. For example, the benzene ratio QC flag is “benz_ratio_status”. The flag values are the same for all analytes and are provided in Table 3.

Table 3. QC flag value descriptions

QC Flag

Flag Meaning

Description

1

Valid

2

Preliminary

Sample measurement is preliminary and has not yet been carefully examined by the PI

3

Deselected

Sample measurement is likely valid but does not meet selection criteria determined by the goals of the CARVE investigation

4

Rejected

Obvious problems during collection or analysis

代码

!pip install leafmap
!pip install pandas
!pip install folium
!pip install matplotlib
!pip install mapclassify
 
import pandas as pd
import leafmap
 
url = "https://github.com/opengeos/NASA-Earth-Data"
df = pd.read_csv(url, sep="\t")
df
 
leafmap.nasa_data_login()
 
 
results, gdf = leafmap.nasa_data_search(
    short_name="CARVE_L2_Flask_1404
",
    cloud_hosted=True,
    bounding_box=(-167.48, 35.15, -106.29, 71.5),
    temporal=("2012-05-23", "2015-11-12"),
    count=-1,  # use -1 to return all datasets
    return_gdf=True,
)
 
 
gdf.explore()
 
#leafmap.nasa_data_download(results[:5], out_dir="data")

引用

All measurements are reported as dry air mole fractions on their respective World Meteorological Organization (WMO) standard scales:

  • NOAA 2004 CO standard scale (see Novelli et al., 1991)
  • NOAA 2007 CO2 standard scale (see Zhao and Tans, 2006)
  • NOAA 2004 CH4 standard scale (see Dlugokencky et al., 2005)
  • NOAA 2004 CMDL H2 standard scale (Novelli et al., 1999)
  • NOAA 2006A N2O standard scale (Hall et al., 2007)
  • NOAA 2006 SF6 standard scale (Hall et al., 2011)

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